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Downhole scale deposition in the Khuff sour gas wells in Saudi Arabia has been a persistent problem, which negatively affects operation and production. Scale deposits are composed of predominantly iron sulfides with other types of minerals also present. Mechanical descaling treatment, although expensive and time-consuming, is often required. Effective scale dissolver is highly desirable to enhance descaling efficiency and to reduce treatment cost. An ideal dissolver is required to have high scale dissolving power, no damage to downhole completion and well productivity, and minimal H2S liberation. This paper presents the laboratory studies on the new scale dissolvers developed by service companies. These products have pH values ranging from strong acidic (pH < 2) to high alkaline (pH > 12). Dissolvers were evaluated for thermal stability, corrosivity to mild steel, and compatibility with formation water at downhole temperatures. The potentials of iron sulfide re-precipitation in spent solutions and free H2S generation were also examined. The qualified chemicals were then evaluated for their dissolving capacity using authigenic pyrrhotite and field scales at elevated temperatures. The obtained results show that most effective acidic dissolvers evaluated in this study were very aggressive to low alloy carbon steel at downhole temperatures. For these with acceptable corrosivity, formation of iron sulfide reprecipitation in spent dissolvers and the generation of a large quantity of free H2S gas also prevented them from field application. Some dissolver products were disqualified due to incompatibility with formation water. Dissolvers with near neutral and alkaline pH values, in general, were inefficient to dissolve the heterogeneous iron sulfide scales. The performance of tested dissolvers varied with scales from different wells, attributed by differences in composition, microstructure, and the presence of hydrocarbon. Results also suggested that pyrite and marcasite were possibly formed during the dissolution process. This paper presents an objective assessment on the currently available iron sulfide scale dissolvers, highlights the challenges on downhole scale dissolution in high temperature sour wells, and provides new insights on the scale dissolution process. The results suggest that further R&D efforts are required to develop more effective chemical solutions to mitigate the iron sulfide scale problem.
Downhole scale deposition in the Khuff sour gas wells in Saudi Arabia has been a persistent problem, which negatively affects operation and production. Scale deposits are composed of predominantly iron sulfides with other types of minerals also present. Mechanical descaling treatment, although expensive and time-consuming, is often required. Effective scale dissolver is highly desirable to enhance descaling efficiency and to reduce treatment cost. An ideal dissolver is required to have high scale dissolving power, no damage to downhole completion and well productivity, and minimal H2S liberation. This paper presents the laboratory studies on the new scale dissolvers developed by service companies. These products have pH values ranging from strong acidic (pH < 2) to high alkaline (pH > 12). Dissolvers were evaluated for thermal stability, corrosivity to mild steel, and compatibility with formation water at downhole temperatures. The potentials of iron sulfide re-precipitation in spent solutions and free H2S generation were also examined. The qualified chemicals were then evaluated for their dissolving capacity using authigenic pyrrhotite and field scales at elevated temperatures. The obtained results show that most effective acidic dissolvers evaluated in this study were very aggressive to low alloy carbon steel at downhole temperatures. For these with acceptable corrosivity, formation of iron sulfide reprecipitation in spent dissolvers and the generation of a large quantity of free H2S gas also prevented them from field application. Some dissolver products were disqualified due to incompatibility with formation water. Dissolvers with near neutral and alkaline pH values, in general, were inefficient to dissolve the heterogeneous iron sulfide scales. The performance of tested dissolvers varied with scales from different wells, attributed by differences in composition, microstructure, and the presence of hydrocarbon. Results also suggested that pyrite and marcasite were possibly formed during the dissolution process. This paper presents an objective assessment on the currently available iron sulfide scale dissolvers, highlights the challenges on downhole scale dissolution in high temperature sour wells, and provides new insights on the scale dissolution process. The results suggest that further R&D efforts are required to develop more effective chemical solutions to mitigate the iron sulfide scale problem.
Matrix permeability impact is a key parameter when assessing the suitability of a squeeze scale inhibitor for field application, and this was particularly true for a new polymeric sulfide scale inhibitor chemistry re-engineered for squeeze treating hot, tight, sour gas condensate chalk producer wells for FeS scale mitigation. The new inhibitor molecule physical size and retention/release behavior, combined with the chalk matrix low permeability and loading capacity, provided some initial question marks with respect to both treatment formation damage potential and also squeeze lifetime longevity. Three years and multiple formation damage corefloods later, and the key questions have now largely been answered. The sulfide scale inhibitor has repeatedly shown minimal formation damage impact when deployed in simulated gas condensate well squeezes in low/very low permeability sandstone and carbonate substrates, and in addition, flowback residual scale inhibitor (RSI) returns data has indicated that significant and indeed extended scale squeeze lifetimes are possible. The following technical account details the final validation coreflood performed in the development series, where successful conclusion would allow the inhibitor to progress to field trial. The ‘proof of concept’ (POC) coreflood required that; (1) the ‘bulk manufactured’ inhibitor (synthesized for field trial) show minimal formation damage impact on field analogous tight chalk core when deployed under target well simulated downhole conditions, and (2) provide the same FeS inhibitory performance and flowback residual scale inhibitor (RSI) profile as generated from the multitude of preceding coreflood series. Besides generating comparative critical gas and condensate core permeability data for fluid transmissibility assessment, the core plug used in the POC flood was subject to tomographic analysis for additional structural/integrity assay. An extensive residual scale inhibitor flowback sampling program was performed to generate inhibitor return data for subsequent use in field-trial squeeze treatment design. The POC coreflood was completed successfully and without incident, and demonstrated minimal formation damage to the chalk core. The flowback RSI profile for the new sulfide scale inhibitor indicated that significant and even extended squeeze lifetime was likely for treatments performed in hot, gas condensate, low permeability chalk well horizons.
Formation of iron sulfide scale in the Khuff sour gas wells has been a persistent problem. Accumulation of scale deposits on downhole tubing and liner has resulted in significant operation problems, such as restricting wellbore surveillance, limiting downhole intervention, interfering with downhole logging, and damaging logging tools. Heavy scale deposition can also result in a significant reduction in well productivity when reaching perforated intervals. Extensive efforts have been devoted in recent years to solve this challenge, including scale composition determination, scaling mechanism investigation, evaluation and deployment of various descaling technologies, understanding formation damage mechanism and development of field trials of preventative methods. Removing such scales has been a challenging and complex process. Coiled tubing (CT) mechanical descaling was developed and deployed in the past, by taking advantage of state-of-the-art technologies such as high RPM milling, downhole sensors, foamed cleanup tools and sophisticated surface collecting/well testing equipment. However, CT descaling operations have become limited in recent years, due to reduced downhole pressures in some wells as field matures. This paper summarizes the holistic approach for mitigating scale deposition in highly sour gas wells, with emphasis on the results of field implementation of the newly patented scale dissolver (ISD) technology for dealing with the iron sulfide scales at high temperatures in the highly sour gas wells. Lab studies demonstrated that this chemical product have potentials to be use for both tubing/liner/completion and formation stimulation benefits as well. Field results showed significantly increased gas productivity in conjunction improved well operational factors, as well as retrieved well accessibility. A discussion on the different lab evaluation protocols is also presented and a final update on current scale clean-up strategies and future proposals are included. The results presented in this work represent the lately advancements on iron sulfide scale management. The new scale dissolver technology is under commercialization and can be applied in all various systems such as oil and gas producers, water injectors, and surface handling facilities.
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