Change of liquid water structure under the presence of phosphate anion during changing its kosmotropic character to chaotropic along its deprotonation route

Temperature-Induced Change of Water Structure in Aqueous Solutions of Some Kosmotropic and Chaotropic Salts

“… Structure of the typical Raman spectrum in the OH-stretching region of water molecules acting on different levels of proton-acceptors and proton-donors. D—hydrogen donor, A—hydrogen acceptor [ 26 , 43 ]. …”

“…Several models were built to describe linear or cyclic (H 2 O) n clusters of different sizes (n = 2, 3, 4, …, 60) and spatial clusters either fullerene-like macro (n = 100, 280, 320) structures [ 22 , 23 ] or formed of those cyclic clusters. Previously performed experimental and modelling works showed the temperature dependence of the size and distribution of water clusters and clusters of primary alcohols [ 24 , 25 , 26 , 27 ].…”