Changes in the Buffer Properties of the Restored Lake Complex

Abstract

The objects of this study were lakes Mielenko (LM) (7.8 ha, 1.9 m), Klasztorne Małe (LKM) (13.7 ha, 20.0 m), and Klasztorne Duże (LKD) (57.5 ha, 8.5 m), located in north Poland (Kashubian Lake District). These lakes received raw sanitary and storm wastewater, leading to extreme degradation of these water bodies. This study aimed to present changes in buffer indicators such as reaction, alkalinity, total hardness, and Ca and Mg content that occurred as an effect of their restoration using the sequential application of coagulants as an innovative approach to the phosphorus inactivation method. Sustainable phosphorus inactivation in the study lakes made it possible to achieve nutrient concentrations in the range of values typical for low-trophic lakes. A radical decrease in P concentration in the water resulted in a limitation of production processes. Moreover, after a, it was noticed that the water parameters determining its buffering properties did not show a clear vertical stratification with increasing values toward the bottom. For example, before restoration, the mean e value of alkalinity in LM fluctuated around 2.10 mval/L, and after restoration activities, the average value was 1.97 mval/L. In LKM, the mean alkalinity value in surface water layers was 2.53 mval/L, and in bottom water layers, it was 4.92 mval/L; after restoration treatments, the average alkalinity of surface water was 2.18 mval/L, and in bottom water, it was 2.99 mval/L. In the last LKD, under the influence of the applied restoration, the average alkalinity of surface waters changed from 2.21 to 2.07 mval/L, and in bottom water, it changed from 2.86 to 2.12 mval/L. The values of parameters determining the buffering properties of lake water after restoration activities allow their water to be classified as slightly or medium hard. The changes obtained can be considered beneficial because water that is too hard does not support the development of aquatic organisms, and the values obtained in the study lakes after sustainable restoration are optimal for the construction of plant walls, shells, and fish bones.