Chapter 3

Davidson, G.

doi:10.1016/0010-8545(90)80004-d

Cited by 4 publications

References 438 publications

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Boron–Nitrogen CompoundsBased in part on the article Boron–Nitrogen Compounds by Robert T. Paine which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Bakus

Atwood

2005

Encyclopedia of Inorganic Chemistry

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The majority of this article details the many synthetic routes and compounds that can be accessed in combinations of boron reagents with amines. Lewis acid‐base adducts are the simplest type of compounds, and lead into the more complex aminoboranes and iminoboranes. Owing to their widespread importance and usage, the borazines, pyrazaboles, and polypyrazaolyborates are covered in separate sections. The newly emerging fields of boron–nitrogen cations and boron nitride solid‐state materials are covered in detail.

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Boron–Nitrogen CompoundsBased in part on the article Boron–Nitrogen Compounds by Robert T. Paine which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Bakus

Atwood

2005

Encyclopedia of Inorganic Chemistry

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Boron–Nitrogen CompoundsBased in part on the article Boron–Nitrogen Compounds by Robert T. Paine which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Bakus

Atwood

2005

Encyclopedia of Inorganic and Bioinorganic Chemistry

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In^III‐Phthalocyanine: Darstellung, Eigenschaften und Kristallstruktur von Tetra(n‐butyl)ammonium‐cis‐di(nitrito‐O,O′)phthalocyaninato(2–)indat(III)

A�mann¹,

Ostendorp²,

Homborg³

1995

Zeitschrift anorg allge chemie

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[In(Cl)Pc2−] bildet mit (nBu4N)NO2 in Aceton grün‐blaues (nBu4N)cis[In(NO2)2Pc2−], welches monoklin kristallisiert (RG.: P21/n (14)). Die Nitrit‐Anionen sind als chelatbildende Nitrito‐O,O′ (NO2)‐Liganden an InIII in cis‐Koordination gebunden. Infolgedessen ist InIII oktakoordiniert und befindet sich in einem verzerrten “quadratischen” Antiprisma auf der dem Pc2−‐Liganden zugewandten Seite. Einer der (NO2)‐Liganden hat ähnlich wie freies Nitrit äquivalente NO‐Bindungen, der andere nichtäquivalente. Beide (In,O,N,O)‐Ringe sind nahezu planar (Diederwinkel: 80°). Der Pc2−‐Ligand ist unsymmetrisch konvex verzerrt. Partiell überlappende Paare einander zugewandter Pc2−‐Liganden bilden von den (NO2)‐Liganden begrenzte Doppelschichten, die von den die (nBu4N)+‐Kationen enthaltenden Schichten getrennt sind. Das Zyklovoltammogramm von cis[In(NO2)2Pc2−]− zeigt drei Elektrodenprozesse, die den Redoxpaaren: Pc3−/Pc2− (−0,94 V) < InI/InIII (−0,78 V) < Pc2−/Pc− (0,64 V) zugeordnet werden. Die UV‐VIS‐NIR‐ und Schwingungsspektren werden diskutiert.

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Chapter 3

Cited by 4 publications

References 438 publications

Boron–Nitrogen CompoundsBased in part on the article Boron–Nitrogen Compounds by Robert T. Paine which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Boron–Nitrogen CompoundsBased in part on the article Boron–Nitrogen Compounds by Robert T. Paine which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Boron–Nitrogen CompoundsBased in part on the article Boron–Nitrogen Compounds by Robert T. Paine which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

In^III‐Phthalocyanine: Darstellung, Eigenschaften und Kristallstruktur von Tetra(n‐butyl)ammonium‐cis‐di(nitrito‐O,O′)phthalocyaninato(2–)indat(III)

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Chapter 3

Cited by 4 publications

References 438 publications

Boron–Nitrogen CompoundsBased in part on the article Boron–Nitrogen Compounds by Robert T. Paine which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Boron–Nitrogen CompoundsBased in part on the article Boron–Nitrogen Compounds by Robert T. Paine which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Boron–Nitrogen CompoundsBased in part on the article Boron–Nitrogen Compounds by Robert T. Paine which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

InIII‐Phthalocyanine: Darstellung, Eigenschaften und Kristallstruktur von Tetra(n‐butyl)ammonium‐cis‐di(nitrito‐O,O′)phthalocyaninato(2–)indat(III)

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In^III‐Phthalocyanine: Darstellung, Eigenschaften und Kristallstruktur von Tetra(n‐butyl)ammonium‐cis‐di(nitrito‐O,O′)phthalocyaninato(2–)indat(III)