Spray wall-impingement has large effects on the pollutant emissions and thermal efficiency of engines. Different wall temperatures can affect the gas-liquid phase transition of the spray, and the temperature gradient from the ambient to the wall will cause a different mixture process in the region nearby the wall. However, there are few studies on spray wall-impingement with different wall temperatures, particularly on the liquid-gas phase transition of the spray. Therefore, in this paper, the effects of different wall temperatures on spray-impingement have been investigated in a high-temperature, high-pressure constant volume combustion vessel. Cooling equipment was used to adjust the temperature difference between the wall and the ambient gas. n-Dodecane was chosen as the diesel surrogate to study the spray process. The spray wall-impingement was tested by changing the injection pressures (P i ) and wall temperatures (T w ). The ambient temperature (T a ) and ambient pressure (P a ) were kept constant at 773 K and 4 MPa, and the distance (L) between wall and injector was set to 35 mm to mimic the radius of the combustion chamber in heavy-duty diesel engines. A laser-induced exciplex fluorescence (LIEF) technique was used to probe the vapor and liquid phases of the injected fuel. Results show that the liquid phases of the spray do not reach the wall except in the condition of low wall temperature and high injection pressure. The liquid penetration develops and then becomes constant after 1 ms from the start of injection. With the increase of injection pressures (600-1600 bar), the liquid concentration of the spray decreases; however the liquid penetration decreases insignificantly. The wall temperature and the injection pressure have little influence on the liquid interpenetration process. For the vapor phase of the spray, the high concentration regions (equivalence ratio (φ) > 1) mainly distribute in the area of 10 mm away from the impact point on the wall. With the decrease of wall temperatures, the high-concentration regions are enlarged at the near wall regions. However, at the injection pressure of 1600 bar, the influence of wall temperatures on the equivalence ratio is small. The decreasing wall temperature deteriorates the mixing process of the fuel and ambient gas, but the effect is weakened with the increase of injection pressure.