During the preparation
of high-strength gasification-coke with
low-rank coal blending, evolution of pyrolysis tar and gas is still
unclear for situations where large amounts of low-rank coal are blended.
Herein, the effect of low-rank coal blending on the distribution of
coking products was thoroughly investigated and the mechanism of tar
lightening was studied by simulating the coking process with 1 kg
laboratory-scale coke oven. The results showed that more liquids but
less gases were formed compared to the theoretically calculated values
due to a stronger cohesive interaction in the coal blending system.
Moreover, the gas yield and volatile matters in dry ash-free basis
(V
daf) showed an opposite linear correlation
for single coal and blended coal, probably due to this strong cohesive
interaction. The facileness of long-chain aliphatic hydrocarbons to
crack into low-molecular-weight hydrocarbons is attributed to their
weaker interactions with more low-rank coal blends. The low-rank coal
blending significantly promoted the release of phenols due to the
presence of hydrogen-donor groups. In addition, more fractured branched
alkanes inhibited the deep condensation of free radicals (cohesive
compounds), which led to tar lightening in the low-rank coal blending
system. In contrast, in the caking coal blending system (without the
addition of low-rank coal), aromatization of fractured olefin terminals
promoted deep condensation of cohesive free radicals, resulting in
the formation of more heavy tar. The current study also demonstrated
that the conversion of heavy tar into light products could be promoted
by adjusting the input of low-rank coal during the caking coal upgrading
process, thereby increasing the profitability of the coking process.