ZnO, as an important semiconductor,
has been extensively studied
for a wide range of applications. To date, with the development of
micro/nano manufacturing technology, various hierarchical ZnO nanostructures
have been fabricated and explored, showing encouraging success in
advanced photodetectors. ZnO nanotube structure has a high surface-to-volume
ratio, and versatile hollow channels, which are promising for sensing
applications. Typical nanotube arrays primarily rely on advanced nanofabrication
technologies. Simple and low-cost fabrication strategies are still
lacking. Herein, we report a simple template fabrication method to
obtain vertically aligned ZnO nanotube arrays. Using flexible, etched
polyimide membranes as the template, ZnO nanotube arrays can be prepared
in situ by dip-coating the sample into a zinc acetate solution followed
by heating. Different hierarchical ZnO nanotube structures were obtained
with the nanotube arrays when the method was combined with hydrothermal
growth. We have demonstrated that the structures may be used in flexible
and transparent photodetectors. Our work provides a facile approach
for fabricating ZnO nanotube arrays and expands the application of
ZnO nanotube structures to flexible and transparent photodetectors.