A fundamental study has been conducted on the effective utilization of rice husk ash (RHA) in concrete. RHA is an agricultural byproduct characterized by silicon dioxide as its main component, with a content of 90% or more and a porous structure that absorbs water during mixing, thereby reducing fluidity. The quality of RHA varies depending on the calcination environment; however, the effect is not consistent. In this study, the pore structure was modified, and fluidity was improved by adjusting the particle size of the RHA. From a quality control perspective, this study aims to classify grades using Luxan values. While the characterization of RHA is based on Luxan values, the methodology for measuring its hydration response has not been reviewed. The test methods used in this study are as follows. To test the raw materials, density, specific surface area, XRF, SEM, and isothermal adsorption–desorption curves were measured, and fluidity was measured in fresh mortar. In a hardened mortar, compressive strength and drying shrinkage length change rate were measured. In addition, XRD and TG were measured for specimens after the compressive strength test. The selective dissolution method was used to measure the hydration rate. By adjusting the particle size of RHA to 45 µm, fluidity was enhanced. The relationship between the Luxan value and the basic properties of the mortar indicates that higher Luxan values correspond to greater compressive strength and drying shrinkage. We believe that the method used in this experiment can be used to quantify RHA.