“…[14][15][16] These coatings are applied on several metal layers such as steel, [17][18][19][20] magnesium, [21][22][23][24][25] galvanized steel, [26][27][28][29][30] and aluminum. 31,32 In general, many phosphate baths are zinc base, 33,34 magnesium base [35][36][37] and iron base 38,39 and by adding di®erent cations such as nickel cation, 40,41 calcium cation, 42,43 niobium cation, 44 and copper cation, two or three cationic baths will be generated. Many of the reported phosphate baths require high operation temperature, the major problem of this bath is that it requires high amount of energy which is recently one of the crises all over the world.…”