Abstract. Aluminium sulphate is one of the most widely used coagulants for water treatment and has been proven to be an effective coagulant for the removal of certain contaminants, turbidity and colour. Aluminium sulphate used during the coagulation process is hydrolyzed in the water, forming polynuclear complexes. Aged aluminium solutions show different coagulation behaviour than that of freshly prepared solutions. The aim of presented research was to highlight the infl uence of the aging of aluminium sulphate solution on the turbidity removal from water. Obtained results reveal that using of optimal aging solution of coagulant improves the coagulation process.Keywords: coagulation, Jar-test, aluminium sulphate, aging.
IntroductionThe quality of river or reservoir water is commonly characterized by the content of suspended solids, colloidal particles, natural organic matter and other soluble, mostly inorganic compounds, present in different concentrations. Therefore, when the river or reservoir water is intended for human consumption, an appropriate treatment process is usually considered as necessary to meet the respective drinking water standards. One of the most important steps during the conventional treatment process is coagulation/fl occulation [1].Coagulation is a common process in water treatment for destabilizing dissolved and colloid impurities and for transforming small particles into larger aggregates (fl ocs) which can be removed from the water in subsequent clarifi cation/fi ltration processes [2][3][4].The coagulation process consists of three sequential steps: coagulant formation, colloid/particle destabilisation, and particle aggregation. Coagulant formation and colloid/particle destabilisation are promoted in a rapid-mixing stage where treatment chemicals are added and dispersed throughout the water to be treated. Particle aggregation (fl oc formation) is then promoted in a fl occulation stage where inter-particles collisions create large fl oc particles amenable to separation from the treated water [3].Aluminium sulphate is one of the most widely used coagulants for water treatment and has been proven to be an effective coagulant for the removal of certain contaminants, turbidity and colour [5][6][7]. When dosed into water the aluminium ions hydrolyse rapidly and in an uncontrolled manner, to form a range of metal hydrolysis species [3].Hydrolysis products may be monomeric or polymeric hydroxyl complexes [8]. Most of them, such as Al(OH)