Characterization and Photoluminescent, Photocatalytic and Antimicrobial Properties of Boron-Doped TiO2 Nanoparticles Obtained by Microwave-Assisted Solvothermic Method

Abstract

Boron doped TiO 2 :xB (x = 0 mol.%, 1 mol.%, 2 mol.%, 4 mol.% and 8 mol.%) was quickly synthesized by a microwave-assisted solvothermic method at 140°C for 10 min. The nanoparticles obtained were characterized by x-ray diffraction (XRD), Fourier transform infrared spectroscopy, Raman spectroscopy, photoluminescence, field emission scanning electron microscopy, electron microscopy and diffuse optical reflectance. The photocatalytic properties were estimated against methylene blue dye. The antimicrobial activity was measured by the disc diffusion technique against S. aureus and E. coli bacteria. The XRD patterns show that there was no formation of secondary phases and that all the peaks correspond to the anatase phase of TiO 2 . Rietveld's refinement showed that the addition of B 3+ in the TiO 2 lattice promotes a reduction in the size of the crystallites and this reduction it effectively increases the degradation capacity of the methylene blue dye, which after 50 min the 8%B sample degraded completely, while the pure TiO 2 sample reduced its concentration by 95%. Boron-doped TiO 2 was effective when reused and after the third cycle the photocatalytic activity of the powders was maintained. In addition, the incorporation of 8%B in the TiO 2 lattice resulted in an increase from 8.66 mm to 15.61 mm and 9.04 mm to 13.65 mm in the inhibition halos of the S. aureus and E. coli bacteria, respectively.

Photocatalytic properties of the CeO2‐xTiO2 and TiO2‐xCeO2 (x = 10, 30, and 50 mol%) heterostructures obtained by a MAH

“…As can be seen from Figure 2A, B and E, F, pure TiO 2 and CeO 2 oxides tend to agglomerate and form nanospheres and nanocubes, respectively. Nanosphere morphology of TiO 2 and nanocubes morphology of CeO 2 are commonly found in the literature for MAH synthesis 32‐36 . According to Zhang et al , 37 morphologies are directly related to the experimental conditions, and the same synthesis method can obtain different morphologies for the same material 13,17 .…”