The phase composition
and distribution characteristics have been
obtained from two mammoth ivory samples with typical blue and yellowish-brown
outer layers. The results reveal that hydroxyapatite, newberyite,
organic matter, and quartz exist in all structures of mammoth ivory.
Vivianite and santabarbaraite mainly contribute to the blue and yellowish-brown
oxide layers of mammoth ivory, respectively. Meanwhile, metavivianite
also occurs and partly influences the appearance of oxide layers.
Vivianite is a common and complex product that can be formed by the
interaction of gradually infiltrated Fe
2+
and the original
PO
4
3–
in mammoth ivory. At the later
stage, vivianite can be oxidized into metavivianite and santabarbaraite.
As a result, mammoth tusks present dark bluish-green and yellowish-brown
appearances. The multi-colored oxide layers are formed by different
contents of vivianite and its oxidation products, which also provides
valuable information on the relative burial intensity and time in
different structures. It is inferred that the burial intensity increases
in the sequence of yellowish-white dentin → blue outer layer
→ yellowish-brown outer layer. These observations are hopeful
to be widely used in evaluating the changeable burial environment
and exploring historical events that occurred on mammoth ivory.