On a first attempt, the determination of 14 C and 36 Cl activity concentrations in basic operational waste (spent ion-exchange resins and perlite mixture), in decommissioning waste (construction concrete, sand, stainless steel and serpentinite) and irradiated graphite from the Ignalina NPP has been performed. The samples for measurement of the specific activity of 14 C and 36 Cl were obtained from the selected places, where the highest values of the dose rate and the activity concentrations of gamma emitters were found. The performed study of the total 14 C and 36 Cl activity concentrations was based on estimated chemical forms of 14 C (inorganic and organic compounds) and 36 Cl as Cl-ion. The tested methods used in this study were found to be suitable for estimation of activity concentrations of measured radionuclides.