Ion beam synthesis of CoSi 2 by Co implantation with a metal vapour vacuum arc ion source has been performed and the effects of substrate temperature on precipitate coarsening and Co distribution in the as-implanted samples have been investigated. The microstructure changes were studied by transmission electron microscopy and the Co distribution shift towards the surface with increasing substrate temperature was observed by Rutherford backscattering spectrometry experiments. Direct measurements of the sputtering depth on masked implanted samples at various substrate temperatures showed that the sputtering yield decreases with increasing temperature. The Co distribution shift phenomenon was explained using a model incorporating both the temperature dependent sputtering yield effect and the precipitate coarsening effect. This model also provides a consistent picture to explain at least partially and qualitatively the observed opposite trends of Co distribution shift towards the surface or the substrate with increasing substrate temperature reported in the literature.