2021
DOI: 10.3390/ma14082058
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Characterization of Charge States in Conducting Organic Nanoparticles by X-ray Photoemission Spectroscopy

Abstract: The metallic and semiconducting character of a large family of organic materials based on the electron donor molecule tetrathiafulvalene (TTF) is rooted in the partial oxidation (charge transfer or mixed valency) of TTF derivatives leading to partially filled molecular orbital-based electronic bands. The intrinsic structure of such complexes, with segregated donor and acceptor molecular chains or planes, leads to anisotropic electronic properties (quasi one-dimensional or two-dimensional) and morphology (needl… Show more

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