The synthesis of nickel silicide
thin films via a vapor–solid
reaction has been studied by exposing thin (10 nm) Ni films to silane
(SiH4). The crystalline phases, the Ni/Si stoichiometric
ratios, as well as the surface and interface properties of the resulting
silicide films were investigated as a function of the growth parameters
such as the SiH4 partial pressure, the reaction temperature,
and the exposure time. At low temperature (300 °C), SiH4 exposure led to the self-limiting deposition of Si on Ni by catalytic
decomposition of SiH4 but not to silicate formation. Between
350 and 400 °C, phase pure orthorhombic NiSi films were obtained
that were formed directly without any apparent intermediate Ni-rich
silicide phases. A transformation to NiSi2 occurred at
450 °C and above, and at 500 °C phase pure NiSi2 was obtained. Here, the transient formation of NiSi was observed
that transformed into NiSi2 for prolonged SiH4 exposure. The results indicate that the Si solubility governs the
phase formation sequence whereas kinetics are determined by Ni diffusion
and the reaction rate. Resistivity values of 21 and 36 μΩ
cm were found for the NiSi and NiSi2 thin films, respectively,
corresponding to the values reported for films obtained by solid-state
reactions.