Characterization of Co–Ni–TiO₂ coatings prepared by combined sol-enhanced and pulse current electrodeposition methods

Abstract

This research comprehensively explores the synthesis of Co–Ni–TiO2 coatings employing a hybrid methodology that integrates sol-enhanced and pulse current electrodeposition techniques. The investigation examined the surface morphology and intrinsic properties of Co–Ni–TiO2 coatings, revealing the significant influence of pulse duty cycle variations on the characteristics of coatings. A detailed analysis indicates that a pulse duty cycle of 0.4 optimized the coating’s performance, offering superior attributes compared to other duty cycle settings. The study elucidates that lower duty cycles foster hydrogen evolution reactions on the cathode surface, culminating in the formation of a porous, needle-like coating structure. Conversely, higher duty cycles are found to mitigate the effects of material replenishment, thereby affecting the coating’s quality and performance. The findings of this investigation not only shed light on the critical relationship between the pulse duty cycle and the properties of Co–Ni–TiO2 coatings but also lay a foundational framework for the further refinement and optimization of these coatings for advanced applications.