2010
DOI: 10.1016/j.scitotenv.2010.04.033
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Characterization of cylindrospermopsin chlorination

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Cited by 49 publications
(30 citation statements)
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“…As a consequence, most research on DBP formation from algal toxins has been performed with chlorine. The reaction of cylindrospermopsin with free chlorine leads to the formation of three DBPs: 5-chloro-cylindrospermopsin, cylindrospermopsic acid, and an unnamed by-product with m/z 375.097 (C 13 H 18 N 4 O 7 S) [127]. In the case of microcystins, up to six chlorination DBPs and their respective isomers have been identified: dihydroxy-microcystin, monochloro-microcystin, monochloro-hydroxy-microcystin, monochloro-dihydroxy-microcystin, dichloro-dihydroxy-microcystin, and trichlorohydroxy-microcystin.…”
Section: Pollutant Dbpsmentioning
confidence: 99%
“…As a consequence, most research on DBP formation from algal toxins has been performed with chlorine. The reaction of cylindrospermopsin with free chlorine leads to the formation of three DBPs: 5-chloro-cylindrospermopsin, cylindrospermopsic acid, and an unnamed by-product with m/z 375.097 (C 13 H 18 N 4 O 7 S) [127]. In the case of microcystins, up to six chlorination DBPs and their respective isomers have been identified: dihydroxy-microcystin, monochloro-microcystin, monochloro-hydroxy-microcystin, monochloro-dihydroxy-microcystin, dichloro-dihydroxy-microcystin, and trichlorohydroxy-microcystin.…”
Section: Pollutant Dbpsmentioning
confidence: 99%
“…Some cyanobacterial toxins can be removed by activated carbon via physical adsorption, however, the limited adsorption ability and high cost of activate carbon inhibit its practical application [17]. The effective chemical degradation of CYN by chlorination [18][19][20][21] and ozonation [22] has also been realized, but suffering from long degradation time and high cost. Recently, advanced oxidation processes (AOPs) based on high active hydroxyl radical ( • OH) have been established as an alternative and superior to conventional chemical oxidation for the degradation of CYN [23].…”
Section: Introductionmentioning
confidence: 99%
“…Chlorine has been demonstrated to be an effective oxidant for MCs [68][69][70][71], cylindrospermopsin [72][73][74][75] and saxitoxins [76]. On the other hand, [19,43].…”
Section: Cyanotoxinsmentioning
confidence: 99%