2024
DOI: 10.1002/ange.202417864
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Characterization of Iminobismuthanes and Catalytic Reduction of Organic Azides via Bi(I)/Bi(III) Redox Cycling

Hye Won Moon,
Nils Nöthling,
Markus Leutzsch
et al.

Abstract: We report the stoichiometric and catalytic reactivity of organobismuth(I) complexes with organic azides. Treatment of N,C,N‐pincer bismuthinidenes with organic azides (acyl, sulfonyl, and bulky aryl) results in isolable monomeric iminobismuthanes which can be structurally characterized—including the formal Bi=N double bond—by multinuclear NMR spectroscopy and single‐crystal X‐ray diffraction. Building upon the stoichiometric reactivity of the monomeric iminobismuthanes, catalytic reduction of a broad range of … Show more

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