Abstract:Crystallization of Poly(ether-block-amide) during microinjection molding is investigated using polarized light microscopy, atomic force microscopy, small/wide angle X-ray scattering and differential scanning calorimetry. Special morphologies of micro dumbbell parts, such as spherulitic or spherulite-free core structures and unique spherulite structures generated beneath the skin layers, are examined and explained relative to processing conditions. Nanoindentation tests confirm that both the modulus and hardness of the skin layer are higher than the core layer, regardless of the core structure. Uniaxial tensile testing indicates that Young's modulus, strain at break and yield stress all increase with an increase of skin ratio. The relationship between process, morphology and mechanical properties are systematically studied for micro products. Additionally, by using in-line process monitoring, flow induced crystallization of polymer filling of a dumbbell part is characterized by shear stress and apparent specific work. By comparison with a "short-term shear protocol", shear stress is validated to be a good candidate to characterize the formation of highly oriented structures under an actual microinjection molding process. This may provide a method for in-line control of morphology development and then final properties by controlling the flow conditions.Additional Information:Question ResponsePlease submit a plain text version of your cover letter here.Please note, if you are submitting a revision of your manuscript, there is an opportunity for you to provide your responses to the reviewers later; please do not add them to the cover letter.Dear Editor, Please find attached extensively revised manuscript that addresses all of the reviewers criticisms and queries, along with Support Material.I trust that you will consider this suitable for full review and ultimately for publication in the journal and look forward to hearing from you in due course.
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Michael Gilchrist
Powered by Editorial Manager® and ProduXion Manager® from Aries SystemsABSTRACT. Crystallization of Poly(ether-block-amide) during microinjection molding is investigated using polarized light microscopy, atomic force microscopy, small/wide angle Xray scattering and differential scanning calorimetry. Special morphologies of micro dumbbell parts, such as spherulitic or spherulite-free core structures and unique spherulite structures generated beneath the skin layers, are examined and explained relative to processing conditions. Nanoindentation tests confirm that both the modulus and hardness of the skin layer are higher than the core layer, regardless of the core structure. Uniaxial tensile testing indicates that Young's modulus, strain at break and yield stress all increase with an increase of skin ratio. The relationship between process, morphology and mechanical properties are systematically studied for micro produc...