Characterization of Nanoporous Poly(Lactic Acid) Microfibers Using a Simplified Centrifugal Spinning Method

Abstract

In recent years, great attention has been paid to the development of porous materials with excellent reactivity and absorbency. The poly(lactic acid) (PLA) microfibers with uniform nanopores were successfully prepared by rotary centrifugal spinning using PLA/chloroform solution. Previous research showed that PLA microfibers have extremely high oil absorbing capacity. In this study, the changes in fiber diameter and nanopore diameter of nanoporous PLA microfibers under different fabrication conditions and the adsorption capacity of Prussian blue nanoparticles were systematically evaluated. The results showed that the fiber diameter increased with increasing PLA/chloroform solution concentration. Furthermore, it was found that the amount of adsorbed Prussian blue nanoparticles increased with the increase in fiber diameter. Prussian blue nanoparticles are known to adsorb radioactive materials such as cesium, and are expected to be applied to the recovery of cesium diffused in the atmosphere and ocean.