Characterization of palladium surfaces with (+)-apopinene: Correlation of reaction paths with surface features

An encapsulated Mn(III)-salen complex in NaY was synthesized and characterized, and the catalytic behaviour of the complex was evaluated by the oxidation of styrene. The encapsulation was achieved by two different methodologies designated as the flexible ligand method (A) and the method of in situ complex synthesis (B). The characterizations of the free complex as well as the catalysts with and without the complex were performed by powder X-ray diffraction, scanning electron microscopy, chemical analysis and FT-IR spectroscopy. Both prepared catalysts are active in the oxidation of styrene in the presence of tert-butyl hydroperoxide (tBuOOH) and lead to styrene epoxide and benzaldehyde. The localization of the complex in zeolite plays an important role in the catalytic activity of these heterogeneous catalysts.

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Determination of Mechanism in Heterogeneous Catalysis

Burwell¹

1991

Catalysis

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Characterization of palladium surfaces with (+)-apopinene: Correlation of reaction paths with surface features

Cited by 30 publications

References 29 publications

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Heterogeneous Catalytic Hydrogenation

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Determination of Mechanism in Heterogeneous Catalysis

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