2005
DOI: 10.1016/j.apcata.2005.02.033
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Characterization of Pt-impregnated MCM-41 and MCM-48 and their catalytic performances in selective catalytic reduction for NOx

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Cited by 28 publications
(3 citation statements)
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“…As shown in Figure a, the catalysts with 1 and 2 wt % Pt loading achieved maximum NO x conversions of 47.5 and 49.3% at 180 °C, respectively. Considering the correlations between Pt loading amount and NO x removal efficiency, the intermediate Pt loading of 0.5% is the optimum amount for NO x reduction, which is similar to previous studies. ,, Previous investigation suggests that Pt species (Pt, PtO x ) act as the adsorption sites for reactant and the active sites for surface reaction during the SCR process. The number of active sites available for NO x reduction increased with the increase of the Pt loading, but there was an optimum Pt loading amount (0.5% Pt), at which the number of active sites just meet the needs of NO x SCR reaction. In other words, the Pt content of 0.5% was enough to activate the SCR reaction, while weakening the direct combustion of C 3 H 6 with O 2 .…”
Section: Resultssupporting
confidence: 85%
“…As shown in Figure a, the catalysts with 1 and 2 wt % Pt loading achieved maximum NO x conversions of 47.5 and 49.3% at 180 °C, respectively. Considering the correlations between Pt loading amount and NO x removal efficiency, the intermediate Pt loading of 0.5% is the optimum amount for NO x reduction, which is similar to previous studies. ,, Previous investigation suggests that Pt species (Pt, PtO x ) act as the adsorption sites for reactant and the active sites for surface reaction during the SCR process. The number of active sites available for NO x reduction increased with the increase of the Pt loading, but there was an optimum Pt loading amount (0.5% Pt), at which the number of active sites just meet the needs of NO x SCR reaction. In other words, the Pt content of 0.5% was enough to activate the SCR reaction, while weakening the direct combustion of C 3 H 6 with O 2 .…”
Section: Resultssupporting
confidence: 85%
“…4 , the peak that appears at a high temperature range of about 350–450 °C can be observed over Ru/TiO 2 and Ru/P25 catalyst, and corresponds to the strong acid sites. 50 In addition, the intensity of NH 3 desorption peak of Ru/TiO 2 catalyst is higher than those of Ru/P25, Ru/Si-beta and Ru/CeO 2 catalysts, indicating Ru/TiO 2 catalyst has abundant acid sites on its surface between 100 and 500 °C. Previous studies shows that the catalysts with abundant acid sites is beneficial for the adsorption of Cl and the cleavage of C–Cl bonds during the DCM catalytic oxidation process.…”
Section: Resultsmentioning
confidence: 94%
“…Zeolite-type catalysts showed excellent catalytic properties in HC-SCR due to their unique pore-channel structure and ion exchangeability. A series of MCM zeolite with high surface area, high thermal stability and big pore volume, have attracted considerable interest for the application as a catalyst or catalyst support [20][21][22][23][24] in the HC-SCR. MCM-49, a new member of this series of zeolite, was discovered by Bennett et al [25].…”
Section: Introductionmentioning
confidence: 99%