2012
DOI: 10.1080/17415993.2012.662669
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Characterization of synthesized poly(aryldisulfide) through interfacial polymerization using phase-transfer catalyst

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2012
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Cited by 27 publications
(8 citation statements)
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“…This behavior leads to an increment in the average molecular weight of polymer, which noticeably affects the properties of polysulfide polymer. 15 Besides, in situ polymerization technique has been reported as an efficient method for the preparation of polymeric nanocomposites in literature. [16][17][18][19] This method involves the polymerization of polymeric monomers in the presence of macro-or nanoparticles, which leads to a high degree of filler dispersion and distribution.…”
Section: Introductionmentioning
confidence: 99%
“…This behavior leads to an increment in the average molecular weight of polymer, which noticeably affects the properties of polysulfide polymer. 15 Besides, in situ polymerization technique has been reported as an efficient method for the preparation of polymeric nanocomposites in literature. [16][17][18][19] This method involves the polymerization of polymeric monomers in the presence of macro-or nanoparticles, which leads to a high degree of filler dispersion and distribution.…”
Section: Introductionmentioning
confidence: 99%
“…Interfacial polymerization using phase transfer catalyst is preferred owing to the high degree of purity and efficiency in separation, mild reaction condition, high yield and high molecular weights at low conversions of reacting groups. [15][16]12] Quaternary ammonium and phosphonium salts, poly(ethyleneglycol), cryptates and crown ethers are certain examples for phase transfer catalysts. [17] Linear polysulfides namely poly(methylene disulfide) and poly(ethylene disulfide) are synthesized by using benzyltriethylammonium chloride found to have thermal stability in the range of 255-260 °C.…”
Section: Polysulfides Through Polycondensationmentioning
confidence: 99%
“…Most of the commercial preparation of polysulfide is through the reaction between alkyl chlorides and sodium polysulfide. [12] Use of mixed dihalide monomer in the condensation polymerization process leads to random copolymers. For making block copolymers, it is required to make individual mercaptan-terminated polymers and blending them in a desired proportions.…”
Section: Polysulfides Through Polycondensationmentioning
confidence: 99%
“…This class of materials shows great resistance against gases, organic solvents, and ozone effects [3][4][5]. Incorporation of a sulfide linkage into a polymer backbone causes an increase in solvent resistance and other properties of polymer [6][7][8][9][10]. On the other hand, aromatic polydisulfide polymers have superior resistance against environmental degradation, low water-vapor transmission, excellent resistance against acids and bases, and good adhesion to metals [11][12][13].…”
Section: Introductionmentioning
confidence: 99%