The stiffness in the top surface of many biological entities
like
cornea or articular cartilage, as well as chemically cross-linked
synthetic hydrogels, can be significantly lower or more compliant
than the bulk. When such a heterogeneous surface comes into contact,
the contacting load is distributed differently from typical contact
models. The mechanical response under indentation loading of a surface
with a gradient of stiffness is a complex, integrated response that
necessarily includes the heterogeneity. In this work, we identify
empirical contact models between a rigid indenter and gradient elastic
surfaces by numerically simulating quasi-static indentation. Three
key case studies revealed the specific ways in which (I) continuous
gradients, (II) laminate-layer gradients, and (III) alternating gradients
generate new contact mechanics at the shallow-depth limit. Validation
of the simulation-generated models was done by micro- and nanoindentation
experiments on polyacrylamide samples synthesized to have a softer
gradient surface layer. The field of stress and stretch in the subsurface
as visualized from the simulations also reveals that the gradient
layers become confined, which pushes the stretch fields closer to
the surface and radially outward. Thus, contact areas are larger than
expected, and average contact pressures are lower than predicted by
the Hertz model. The overall findings of this work are new contact
models and the mechanisms by which they change. These models allow
a more accurate interpretation of the plethora of indentation data
on surface gradient soft matter (biological and synthetic) as well
as a better prediction of the force response to gradient soft surfaces.
This work provides examples of how gradient hydrogel surfaces control
the subsurface stress distribution and loading response.