h i g h l i g h t sThe diffusion bonding of Ti 3 SiC 2 and Ti 2 AlC to Zircaloy-4 cladding was investigated. Si penetration into the Zr-4 was roughly an order of magnitude less than that of Al. The resultant bonds using Ti 2 AlC were weak and full of cracks. The Ti 3 SiC 2 /Zr-4 bonds were stronger, and withstood the forces of sectioning.
a b s t r a c tHerein, we report on the interactions between zirconium, in the form of Zircaloy-4 (Zr-4) and the MAX phases, Ti 3 SiC 2 and Ti 2 AlC in the 1100-1300°C range. In both cases, the A-group element, Al or Si, diffused out of the MAX phases and formed intermetallics with the Zr-4. Under comparable conditions, Si penetration into the Zr-4 was roughly an order of magnitude less than that of the Al from the Ti 2 AlC. The effective diffusion coefficient of Si can be described by D eff Si m 2 s ¼ 7:4 Â 10 À9 exp À170 kJ=mol RT ð Þ ; that of Al by D eff Al m 2 s ¼ 9:3 Â 10 À12 exp À38 kJ=mol RT ð Þ . At 38 kJ/mol, the activation energy for the Ti 2 AlC/Zr-4 diffusion bonding process was significantly lower than that of the Ti 3 SiC 2 /Zr-4 diffusion couples, at 170 kJ/mol.