Characterization of the olfactory impact around a wastewater treatment plant: Optimization and validation of a hydrogen sulfide determination procedure based on passive diffusion sampling

Abstract

A monitoring program based on an indirect method was conducted to assess the approximation of the olfactory impact in several wastewater treatment plants (in the present work, only one is shown). The method uses H 2 S passive sampling using Palmes-type diffusion tubes impregnated with silver nitrate and fluorometric analysis employing fluorescein mercuric acetate. The analytical procedure was validated in the exposure chamber. Exposure periods of at least 4 days are recommended. The quantification limit of the procedure is 0.61 ppb for a 5-day sampling, which allows the H 2 S immission (ground concentration) level to be measured within its low odor threshold, from 0.5 to 300 ppb. Experimental results suggest an exposure time greater than 4 days, while recovery efficiency of the procedure, 93.0 AE 1.8%, seems not to depend on the amount of H 2 S collected by the samplers within their application range. The repeatability, expressed as relative standard deviation, is lower than 7%, which is within the limits normally accepted for this type of sampler. Statistical comparison showed that this procedure and the reference method provide analogous accuracy. The proposed procedure was applied in two experimental campaigns, one intensive and the other extensive, and concentrations within the H 2 S low odor threshold were quantified at each sampling point. From these results, it can be concluded that the procedure shows good potential for monitoring the olfactory impact around facilities where H 2 S emissions are dominant.Implications: Passive samplers are very attractive tools to experimentally tackle a number of air pollution problems, especially those related to odor impact. Their small size and cost permit a denser sampling design and thus a more detailed spatial characterization than other techniques. On the other hand, the large inherent variability in passive sampler measures requires an uncertainty analysis of the chemical species and analytical procedures used.

Small Molecule Optical Probes for Detection of H2S in Water Samples: A Review

“…H 2 S can be generated during industrial processes through protonation of HS – and sulfide (S 2– ), which are extensively used to produce sulfur, sulfuric acid, dyes, detergents, cosmetics, etc. and moreover through the oxidation/degradation/disintegration of sulfur-rich amino acid residues in meat proteins, as well as several organic compounds produced in paper, petrochemical treatment, biogas production, printing, mining, leather manufacturing, dyeing industries, and sewage treatment plants. − Large amounts of sulfur containing wastewater are generated due to the rapid advancements in industries.…”

“…and moreover through the oxidation/degradation/disintegration of sulfur-rich amino acid residues in meat proteins, as well as several organic compounds produced in paper, petrochemical treatment, biogas production, printing, mining, leather manufacturing, dyeing industries, and sewage treatment plants. 2 − 8 Large amounts of sulfur containing wastewater are generated due to the rapid advancements in industries.…”

Portable and Disposable Paper-Based Fluorescent Sensor for In Situ Gaseous Hydrogen Sulfide Determination in Near Real-Time

“…Anthropogenic emissions of H 2 S are related to the extraction and refining of oil and natural gas, sewage treatment plants, manure-handling plants, and tanneries. , Most of these processes produce hydrogen sulfide as an industrial byproduct and can cause episodes of high concentrations of the gas (from hundreds of ppb to hundreds of ppm), which can affect public health. Hydrogen sulfide poisoning is the second most common cause of death in workplaces, after carbon monoxide poisoning .…”