<span>We used the ceramic approach to synthesize a sequence of Sr<sub>4</sub>La(PO<sub>4</sub>)<sub>3</sub>O:Ce<sup>3+</sup>,Tb<sup>3+</sup>,Mn<sup>2+</sup> within our study. Especially, the attributes of Sr<sub>4</sub>La(PO<sub>4</sub>)<sub>3</sub>O that were extensively investigate are luminous characteristics, thermal stableness, and energy transfering from Ce<sup>3+</sup> to Tb<sup>3 </sup>and Mn<sup>2+</sup>.Through energy transfer, sensitizer Ce<sup>3+</sup> ions can considerably boost the fragile green radiation from Tb<sup>3+</sup> and red radiation from Mn<sup>2+</sup>. The color of the radiation can be changed by adjusting the Ce<sup>3+</sup>/Tb<sup>3+</sup> and Ce<sup>3+</sup>/Mn<sup>2+</sup> ion ratios. The Sr<sub>4</sub>La(PO<sub>4</sub>)<sub>3</sub>O: 0.12Ce<sup>3+</sup>, 0.3Mn<sup>2+</sup> specimen produced white light having hue coordinates of (0.3326, 0.3298). <span>According to this result, it shows that</span> Sr<sub>4</sub>La(PO<sub>4</sub>)<sub>3</sub>O:Ce<sup>3+</sup>,Tb<sup>3+</sup>,Mn<sup>2+</sup> might be used in white <span>light-emitting diodes (WLEDs).</span></span>