TitleStructure and distribution of inorganic components in the cake layer of a membrane bioreactor treating municipal wastewater. Permalink https://escholarship.org/uc/item/4hw0p6mh
Journal
Highlights• Characterize the structure and distribution of the inorganic in cake layer of MBR.• BCR, XPS and map/line scanning EDX identify the inorganic structure in cake layer.• Si, Al, Ca, Mg, Fe, and Ba are the predominant inorganic compounds in cake layer.• The predominant inorganic compounds are found to occur mostly as crystal particles.• Si and Al accumulate together along the cross-sectional cake layer as SiO2-Al2O3.
AbstractA laboratory-scale submerged anoxic-oxic membrane bioreactor treating municipal wastewater was operated to investigate the structure and distribution of the inorganic cake layer buildup on the membrane. BCR (European Community Bureau of Reference) sequential extraction, X-ray photoelectron spectroscopy (XPS), and both map and line scan of energy-dispersive X-ray analysis (EDX) were performed for cake layer characterization. BCR results showed that Si, Al, Ca, Mg, Fe, and Ba were the predominant inorganic elements in the cake layer, and they occurred mostly as crystal particles. Crystal SiO2 was the dominant inorganic compound while Ca in the form of CaSO4 (dominant) and CaCO3 were also present, but exerted little effect on the cake layer structure because most of these compounds were deposited as precipitates on the reactor bottom. EDX results indicated that Si and Al accumulated together along the cross-sectional cake layer in the form of Si-Al (SiO2-Al2O3) crystal particles.
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