Charge attachment–induced transport: toward new paradigms in solid state electrochemistry

Weitzel, Karl‐Michael

doi:10.1016/j.coelec.2020.100672

Cited by 4 publications

(1 citation statement)

References 49 publications

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“…Whether corresponding calculations can be carried out in a reliable manner also by fast numerical solutions of equations, as done here for dc-conductivities and their activations energies, is an open problem. A recently developed experimental technique is the charge attachment induced ion transport (CAIT) [50][51][52], where collective diffusion coefficients of mobile ions are extracted by a modelling of diffusion profiles. A particular merit of the CAIT method is that mobile ions of different types can be directly injected in the glassy phase.…”

Section: Discussionmentioning

confidence: 99%

Predicting conductivities of alkali borophosphate glasses based on site energy distributions derived from network former unit concentrations

Bosi¹,

Maass²

2021

Preprint

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Section: Discussionmentioning

confidence: 99%

Predicting conductivities of alkali borophosphate glasses based on site energy distributions derived from network former unit concentrations

Bosi¹,

Maass²

2021

Preprint

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Measurements and Utilization of Consistent Gibbs Energies of Transfer of Single Ions: Towards a Unified Redox Potential Scale for All Solvents

Radtke

Gebel

Priester

et al. 2022

Chemistry A European J

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Utilizing the “ideal” ionic liquid salt bridge to measure Gibbs energies of transfer of silver ions between the solvents water, acetonitrile, propylene carbonate and dimethylformamide results in a consistent data set with a precision of 0.6 kJ mol−1 over 87 measurements in 10 half‐cells. This forms the basis for a coherent experimental thermodynamic framework of ion solvation chemistry. In addition, we define the solvent independent peabsH2normalO ‐ and the EabsH2normalO values that account for the electronating potential of any redox system similar to the pHabsH2normalO value of a medium that accounts for its protonating potential. This EabsH2normalO scale is thermodynamically well‐defined enabling a straightforward comparison of the redox potentials (reducities) of all media with respect to the aqueous redox potential scale, hence unifying all conventional solvents′ redox potential scales. Thus, using the Gibbs energy of transfer of the silver ion published herein, one can convert and unify all hitherto published redox potentials measured, for example, against ferrocene, to the EabsH2normalO scale.

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Dielectric breakdown of oxide films in electronic devices

Padovani,

La Torraca,

Strand

et al. 2024

Nat Rev Mater

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Charge attachment–induced transport: toward new paradigms in solid state electrochemistry

Cited by 4 publications

References 49 publications

Predicting conductivities of alkali borophosphate glasses based on site energy distributions derived from network former unit concentrations

Predicting conductivities of alkali borophosphate glasses based on site energy distributions derived from network former unit concentrations

Measurements and Utilization of Consistent Gibbs Energies of Transfer of Single Ions: Towards a Unified Redox Potential Scale for All Solvents

Dielectric breakdown of oxide films in electronic devices

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