Charge‐Reversible Surfactant‐Induced Transformation Between Oil‐in‐Dispersion Emulsions and Pickering Emulsions

Abstract

A novel charge‐reversible surfactant, (CH3)2N‐(CH2)10COONa, was designed and synthesized, which together with silica nanoparticles can stabilize a smart n‐octane‐in‐water emulsion responsive to pH. At high pH (9.3) the surfactant is anionic carboxylate, which together with the negatively charged silica nanoparticles co‐stabilize flowable oil‐in‐dispersion emulsions, whereas at low pH (4.1) it is turned to cationic form by forming amine salt which can hydrophobize in situ the negatively charged silica nanoparticles to stabilize viscous oil‐in‐water (O/W) Pickering emulsions. At neutral pH (7.5), however, this surfactant is converted to zwitterionic form, which only weakly hydrophobises the silica particles to stabilize O/W Pickering emulsions of large droplet size. Moreover, demulsification can be achieved rapidly triggered by pH. With this strategy particles can be controlled either dispersed in water or adsorbed at the oil‐water interface endowing emulsions with the capacity for intelligent and precise control of stability as well as viscosity and droplet size.

Redox- and pH-responsive emulsions based on TiO2 nanoparticles and ferrocene derivates

“…In order to verify this, the emulsifier was collected by centrifugation and FTIR measurement was carried out. 40 Fig. 3 shows the FTIR spectra of FcA, TiO 2 nanoparticles and emulsifiers collected from emulsions.…”

“…As can be seen, the mean diameter of the oil droplet decreased upon increasing the content of TiO 2 nanoparticles, which also proved the adsorption of TiO 2 nanoparticles at the oil-water interface. 40 Moreover, long-term storage stability of emulsions was assessed by storing emulsions at room temperature for seven days and one month, and the results are shown in Fig. S10 (ESI †).…”