Charge Transfer Bands in Zn<sup>+</sup> Doped Potassium Halides

Moreno, M.

doi:10.1002/pssb.2220980152

Physica Status Solidi (b)

1980

DOI: 10.1002/pssb.2220980152

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Charge Transfer Bands in Zn⁺ Doped Potassium Halides

M. Moreno

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1981

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Cited by 4 publications

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A Study about the Optical Absorption Spectra of KCl:Hg⁺

Moreno

1981

Physica Status Solidi (b)

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A Study about the Optical Absorption Spectra of KC1:hg' BY M. MORENO Baranov e t al. / I / have recently reporled strong evidencw about the formation of Fig+ at cationic positions in KCl c r y s t a l s doped with HgC12 and subjected to X-ray irradiation. The correlation between the ESR and optical absorption (OA)data clearly indicates that three OA bands peaked at 4.30, 4.59, and 5.12 eV are due to Hg+ /l/. Up to now, however, no assignment of such bands has bpen

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A Study about the Optical Absorption Spectra of KCl:Hg⁺

Moreno

1981

Physica Status Solidi (b)

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Optical spectroscopy of Mn2+ ions in solid solution and Suzuki phase in NaCl single crystals

Rodrı́guez

Moreno

Jaqué

et al. 1983

The Journal of Chemical Physics

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The optical spectroscopy of Mn'+ ions both in dipolar form and forming Suzuki-phase precipitates has been studied in NaCl by photostimulated luminescence at room and liquid nitrogen temperatures. An analysis of the positions of the crystal field transitions shows that the 10 Dq value is slightly higher (about 7%) in the Suzuki than in the dipolar phase while the covalency is the same in both cases. Such analysis allows us to estimate the value I" -/~ = 4.8% from the optical data which is in agreement with the EPR data for [Mnel,]' -clusters. Moreover, an intense band peaking at 231 nm which disappears when the dipolar phase is formed has been ascertained to be associated with the Suzuki phase. This band has been assigned to the double excitation 'A ItS) + 'A ItS) -> 'T,(G) + [4A ,(G). 4E(G)]; that is consistent with the existence of Mn'+ ions in close positions in the Suzuki phase.

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s¹ions in alkali halides: Ligand relaxation and g-shift

Barriuso¹,

Moreno²

1983

Radiation Effects

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Charge Transfer Bands in Zn⁺ Doped Potassium Halides

Cited by 4 publications

References 8 publications

A Study about the Optical Absorption Spectra of KCl:Hg⁺

A Study about the Optical Absorption Spectra of KCl:Hg⁺

Optical spectroscopy of Mn2+ ions in solid solution and Suzuki phase in NaCl single crystals

s¹ions in alkali halides: Ligand relaxation and g-shift

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Charge Transfer Bands in Zn+ Doped Potassium Halides

Cited by 4 publications

References 8 publications

A Study about the Optical Absorption Spectra of KCl:Hg+

A Study about the Optical Absorption Spectra of KCl:Hg+

Optical spectroscopy of Mn2+ ions in solid solution and Suzuki phase in NaCl single crystals

s1ions in alkali halides: Ligand relaxation and g-shift

Contact Info

Product

Resources

About

Charge Transfer Bands in Zn⁺ Doped Potassium Halides

A Study about the Optical Absorption Spectra of KCl:Hg⁺

A Study about the Optical Absorption Spectra of KCl:Hg⁺

s¹ions in alkali halides: Ligand relaxation and g-shift