“…Expansion of p in the basis of irreducible tensor operators T~ < 28 ) (25) where the components with k = 0, 1, 2 can be associated with "population," "orientation," and "alignment" of magnetic sublevels of terms with orbital angular momenta L. Fine and hyperfine interactions with splittings hw1F,F, yield the time dependences for [(LS)1I]F terms with lifetime T (26) This transfer of anisotropy between orbital angular momenta and electronic/nuclear spins given by equation (26) can be used to perform high-resolution atomic spectroscopy< 30 l and to produce spin-polarized beams after ion-surface scattering.< 31 l The anisotropic sublevel populations of excited terms are generally probed by the polarization of the fluorescence light emitted in transitions between terms with orbital angular momenta L, L 0 • Since after grazing ion-surface scattering the orientation of orbital angular momenta plays a dominant role with respect to the anisotropy obtained, we limit our discussion to the normalized Stokes parameter (27) where I(u-), I(u+) are the intensities of light with negative and positive helicity, respectively. S/ I (and the Stokes parameter describing the linear polarization fraction) is directly related to the tensorial components of the density operator.…”