I would like to thank Prof. Sun changing and Prof. Joe Hsieh. Thanks for their ideas in XPS and XRD measurements, which helped me overcome frustrating barriers in my research. It is my pleasure to acknowledge Dr. Fu yongqing, my partner on XPS experiments and data analysis, who constantly contributed to ideas of my research and showed perseverance during the time of tedious XPS measurements. Thanks to Mr. Ng Chi Yung and Ms. Huang Jiayi for assistance in experiments and useful discussions. I gratefully acknowledge Professor Tse Man Siu, and Mr. Ho Po Fung for their help on process development. The help given by staff members in the Micro-Fabrication Laboratory, especially Mr. Ho for the sample fabrication is greatly appreciated. I record my sincere thanks to the technical staff: Ms.