We complete the set of QCD light-cone sum rules for B → ππ transition form factors, deriving a new sum rule for the timelike-helicity form factor F t in terms of dipion distribution amplitudes. This sum rule, in the leading twist-two approximation, is directly related to the pion vector form factor. Employing a relation between F t and other B → ππ form factors, we obtain also the longitudinal-helicity form factor F 0 . In this way, all four (axial-)vector B → ππ form factors are predicted from light-cone sum rules with dipion distribution amplitudes. These results are valid for small dipion masses with large momentum.