The aim of this thesis is to develop a methodology to model and simulate the dynamics of Organic Rankine Cycle (ORC) power plants, and to demonstrate and validate this methodology by performing experiments on a laboratory-scale ORC plant. Typical plant models for ORCs provide steady state analysis of thermodynamic cycles and losses, but for a system that has complex starting mechanisms and undergoes fluctuations in operating conditions due to environmental effects, dynamic models are needed to predict how the system will behave. Two main questions are interesting to an ORC designer. What is the start-up and shut-down time of the plant? And: What effect does an unprecedented slow or sharp transient in one or multiple physical variables have on the system? There are a number of modelling libraries available for the simulation of Rankine cycles, however there is no complete package that covers all potential dynamic scenarios and is fully documented with guidance on how to develop a stable dynamic model. Issues such as component selection and parameterisation criteria, compilation of stable models in large systems, simulation initialisation strategies, and heat transfer model selection present many challenges to the inexperienced modeller. This thesis aims to address these issues and document strategies to overcome them.Existing modelling libraries do not include extensive heat transfer models that can accurately simulate the heat exchange that occurs during dynamic transients in ORC heat exchangers. Void fraction is a critical variable for the dynamics of a closed thermodynamic cycle that depends on accurate heat transfer models, and models that switch between single-phase and two-phase heat transfer correlation are beneficial here. Development of an extension of the existing heat transfer models to better model these effects is another aim of this thesis.A smaller ORC laboratory that is separate to the main facility used in this project was available early in the thesis to test initial heat exchanger and cycle modelling results. An intermediate project goal was to use this laboratory to model and analyse a novel small-scale solar cogeneration unit that uses cheap and available components to heat water and produce power using a scroll expander. The completion of this goal was seen as a fundamental step toward understanding the physical characteristics of an ORC that is producing power, and to observe the system dynamics. The results of i the study include a typical day's power output for various times of the year, and show the competitiveness of this type of system.The major contributions that originate from the main body of work on the larger ORC facility are:• Development of extended pipe models that include an extra wall for heat transfer to a shell or the environment;• Development of detailed, deterministic plate heat exchanger models with descriptive parameters that can be quickly configured by an inexperienced modeller. These include extensions to heat transfer models and a new phase switching method ...