Chelating properties of permethylated 6A,6D-dideoxy-6A,6D-bis(1-imidazolyl)cyclodextrins towards Pt(II) and Ru(III)

Abstract

Two imidazole-coordinating groups have been successfully grafted onto the C-6 A and C-6 D positions of permethylated aand b-cyclodextrin scaffolds. Both water-soluble ligands L1

Platinum‐Imidazolyl Schiff Base Complexes Immobilized in Periodic Mesoporous Organosilica Frameworks as Catalysts for Hydrosilylation

“…[20][21][22][23][24][25][26] In fact, the imidazolyl moiety itself is a fine chelating agent towards platinum due to the electron donating N atoms on its rigid ring, and several platinum-imidazolyl complexes have been reported in the literature. [27][28][29][30] When it is further converted into a Schiff base, its chelating ability is further enhanced as the number of donating atoms increase, thus increasing its ability to form platinum complexes.…”