“…Overall, the use of produced waters with high Na + will result in enhanced swelling, while a high background K + or addition of KCl to reinjected water may aid in inhibiting swelling. - Crystalline swelling, This stepwise process is caused by the hydration of the exchangeable cations of the clay (with lower water content) resulting in adsorption of multiple discrete layers of water on the clay surfaces. , Negatively charged clay layers are held together by the interlayer cations that hydrate upon interaction with the polar water molecules, rearranging such that spacing is increased between the clay layers. , This interlayer spacing is dependent on the thermodynamic potential that is constrained by the pH, temperature, and pressure
- Dispersion, Dispersion is a rapid process in which individual layers of the clay mineral are separated and dispersed in solution with no interactions between the layers. , Hydration of clay minerals causes the pore pressure to be greater than the strength of the bond between the clay minerals and results in exfoliation of clay blocks into colloidal-size fines . The surface charge, pH, and clay composition are factors that control clay dispersion. − Dispersed smectite clays have variable shapes, for example, the swelling clay Na + -montmorillonite disperses into individual sheet-like layers while the nonswelling kaolinite readily disperses in the presence of water or noninhibiting drilling mud , to form a colloidal suspension. , Studies − have shown that bacterial action can change the surface area, cation exchange capacity, and the layer charge on clays which can impact dispersion.
- Flocculation or aggregation, The addition of polymer macromolecules can destabilize the colloidal dispersion and cause the particles to aggregate and come out of suspension either by bridging the particles (attaching to the surface of two individual particles) or by neutralizing the surface charge on the particle .
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