Chemical and Physical Deterioration of Lithium-ion Battery

Abstract

The life cycle assessment of lithium-ion (Li-ion) rechargeable battery was evaluated by charge and discharge processing. The influence of the temperature was studied during several hundred cycles of charge/discharge process of Li-ion battery. The charging capacity was observed to be decreased with increased number of cycle, especially at higher temperature of the environment of 60℃. The cathode of Li-ion battery was found to be affected by heat stress and charge/discharge cycles by XRD analysis. The GC-FID and GC-MS studies revealed that the diethylfluorophosphate (DEFP) is a degraded product of electrolyte. Though the decomposition of ethylene carbonate (EC), a major component of the electrolyte in the Li-ion battery was not clearly found, the relative area of DEFP to that of EC was found to be increased with increased charge /discharge cycle number at 60℃ .

Urgent Needs for Second Life Using and Recycling Design of Wasted E-car Lithium-ion Battery: A Scientometric Analysis

“…3), Electrochemical technology is a alternate for the extraction of Li and metals. The main bene ts of this technology are that it doesn't harm the environment, is exible, saves energy, is safe, can be used selectively, can be automated, and is cheaper than other technologies(Kato et al, 2014). (4), Biometallurgy or biohydrometallurgy technology as an substitute technique of removal and recovery of treasured metals than other treatment technologies(Hu et al, 2020).…”