1989
DOI: 10.1002/cber.19891220929
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Chemical and spectroscopical evidence for an electron‐transfer mechanism in the reaction of arenesulfonyl chlorides with anions

Abstract: The reaction of amide and amidate anions 2 with ptoluenesulfonyl chloride (1) under Merent reaction conditions gives rise to the total or prrrtial reduction of the acyl halide to p-toluenesulfiaic acid (5) and acylatioo compounds in variable amounts depending on the crowding at the anionic center. This indicates that a SingIe-Electron Transfer (SET) mechanism is involved in the reactions of 1 with anions. Unpaired electron species are detected by RTR in the course of the reactions.It is well-established that s… Show more

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Cited by 4 publications
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