Chemical Characterization and Modification of Lignins

Depolymerization and modification of lignin have been achieved simultaneously in a one-pot chemical reaction. Two heteroelement-rich modifiers, imidazol-1-yl phosphonic dichloride and 1H-1,2,4-triazol-1-yl phosphonic dichloride, were selected to react with lignin in this work. The modified lignin (m-lignin) is demonstrated as an effective lubricating additive for [choline][amino acid] ([CH][AA]) bioionic liquids. Different characterization techniques have been utilized to study the lignin depolymerization, reaction between lignin and modifiers and m-lignin/[CH][AA] interaction. The effect of the molecular structure of the modifiers on the rheological and tribological properties of m-lignin/[CH][AA] lubricants was systematically investigated. Density function theory is used to calculate the electronic structure of lignin, m-lignin, and [CH][AA]. The atomic natural charge analysis revealed the most negative charge on nitrogen bonded to a phosphorus atom and the strongest capability of forming hydrogen bonding with [CH][AA]. The introduced nitrogen and phosphorus elements not only increase the hydrogen bonding density in m-lignin/[CH][AA] but also enhance the polarity of the m-lignin, both of which facilitate a strong adhesion of lubricant on a metal surface and thus promote lubrication. A larger fraction of heteroatom groups in m-lignin contributes to a better lubrication property of these lubricants.

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Efficiency comparison of activated carbons prepared in inert and in self-generated atmospheres

Yousfi¹,

Fettaka²,

Velasco

et al. 2020

Materials and Manufacturing Processes

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Chemical Characterization and Modification of Lignins

Cited by 3 publications

References 227 publications

Systematic study of the role played by ZnCl2 during the carbonization of a chemically activated carbon by TG–MS and DSC

Systematic study of the role played by ZnCl2 during the carbonization of a chemically activated carbon by TG–MS and DSC

Enriching Heteroelements in Lignin as Lubricating Additives for Bioionic Liquids

Efficiency comparison of activated carbons prepared in inert and in self-generated atmospheres

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