Chemical Composition Variations of Altered and Unaffected Coals from the Huaibei Coalfield, China: Implications for Maturity

Abstract

The composition characteristics of altered coals in the Huaibei Coalfield, China, was investigated through a comparative analysis between altered and unaffected coals from the Wolonghu, Taoyuan and Renlou coal mines. Results indicated that the altered coals in Wolonghu coal mine are mostly anthracite coals, with a maximum vitrinite reflectance of 1.6–3.9% (average of 2.9%). Coals from Wolonghu coal mine were mainly consisted of vitrinite (66.2–97.0%), followed by inertinite (2.0–4.0%) and exinite (0.4–6.9%). Differences in volatile matter content were observed between the altered coals in Wolonghu coal mine and unaffected coals from neighboring coal mines, implying that the chemical composition and maturity of coals were changed after magmatic alteration. In addition, differences in hydrogen element were noted among the coals from Wolonghu, Renlou and Taoyuan coal mines, and the phenomenon of “deficient in hydrogen element” was observed in Wolonghu coals. The aliphatic hydrocarbon structure parameters suggested that the aliphatic chain lengths of Wolonghu coals are shorter than those of coal samples from the Renlou and Taoyuan coal mines. In addition, maturity is positively correlated with hydrogen enrichment degree, but negatively related with aliphatic hydrocarbon structure. Coals from Renlou and Taoyuan coal mines showed great weight loss with various heating rates at temperatures of 0–1000 °C, whereas those from Wolonghu coal mine had less weight loss.

Correlation Evaluation and Schematic Analysis of Influencing Factors Affecting Pore and Fracture Connectivity on the Microscale and Their Application Discussion in Coal Reservoir Based on X-ray CT Data

“…Based on the vitrinite reflectance testing result (i.e., R o,ma x (%)) of experimental samples and the coal industry standard MT/T1053–2008, 19 the YW and SH samples are anthracite and the RL and PY samples are bituminous coal. Other basic testing results of the four samples are shown in Table 1 .…”