“…Volatile organic compounds (VOCs), which originate from multiple sources such as household items, cooking appliances, paint, oil refineries, and vehicle exhaust emissions, are highly hazardous vapors that significantly affect human health and air quality in various industrial environments. − Despite having been investigated extensively over the past few years, the sensing properties toward VOCs need to be improved continuously to meet the most up-to-date requirements for specific applications and to withstand the harsh industrial environments, especially when using heterostructures or heterojunctions of two or more metal oxides. − The selective detection of low concentrations of VOCs is highly important to underpin the continuous monitoring of human health and for environmental safety . Among the various types of materials available, the semiconducting–metal oxide-based chemo-resistive sensors are considered to be promising candidates for the detection of VOCs, , especially those comprising heterostructures/heterojunctions containing two or more different oxides, as these materials show excellent potential for their application in portable solid-state devices because of their low cost, high efficiency, simple preparation method, and good stability. − In the context of real-world applications, the response parameter is influenced by several factors, including the morphology, microstructure, defects, and heterojunctions of the VOC sensors as well as the relative humidity . The response and selectivity performance of solid-state gas sensors can be improved further through control of their properties and, especially, by developing new multilayered or heterostructured oxides with a coating of Al 2 O 3 nanofilms.…”