2011
DOI: 10.1039/c1jm10921a
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Chemical pathways of epoxidized and hydroxylated fatty acid methyl esters and triglycerides with phosphoric acid

Abstract: Title: Chemical pathways of epoxidized and hydroxylated fatty acid methyl esters and triglycerides with phosphoric acidChemical pathways of epoxidized and hydroxylated triglycerides with phosphoric acid (H 3 PO 4 ) were revealed using fatty acid methyl esters model system. Besides catalyst function, H 3 PO 4 facilitates phosphate ester linkages. Novel transparent tapes were developed based on this chemistry.

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Cited by 43 publications
(17 citation statements)
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“…Epoxidized soybean oil is usually used as lubricants, plasticizers, rubber-like materials and polymer stabilizers in industry (Biermann et al, 2008;Wu et al, 2000;Hwang and Erhan, 2001;Sharma et al, 2006;Campanella et al, 2010;Noor Armylisas et al, 2017). With the rapid development of the oleochemical industry and increasing demand for renewable materials, the interest in using the epoxidized vegetable oil methyl esters as the chemical intermediate is increasing continually, such as carbonate esters and polymers (Mazo and Rios, 2013;Martini et al, 2009;Ahn et al, 2011;Mustata et al, 2014).…”
Section: Introductionmentioning
confidence: 99%
“…Epoxidized soybean oil is usually used as lubricants, plasticizers, rubber-like materials and polymer stabilizers in industry (Biermann et al, 2008;Wu et al, 2000;Hwang and Erhan, 2001;Sharma et al, 2006;Campanella et al, 2010;Noor Armylisas et al, 2017). With the rapid development of the oleochemical industry and increasing demand for renewable materials, the interest in using the epoxidized vegetable oil methyl esters as the chemical intermediate is increasing continually, such as carbonate esters and polymers (Mazo and Rios, 2013;Martini et al, 2009;Ahn et al, 2011;Mustata et al, 2014).…”
Section: Introductionmentioning
confidence: 99%
“…Another application was reported for H 3 PO 4 modified epoxidized and hydroxylated fatty acid methyl esters and triglycerides. In this way formation of the polymer crosslinks was increased via formation of phosphoric acid esters [12]. Phosphoric acid has also been used in numerous works as a catalyst, e.g., of ring opening of epoxy compounds.…”
Section: Phosphoric Acidmentioning
confidence: 99%
“…For instance,they can be used as biofuel [3] (biodiesel) but can be bestc onverted to valuableb uilding blocks for applicationsi np harmaceuticals, cosmetics, paints, coatings, packagingm aterials, lubricants, surfactants, fine chemicals and polymers. [4] Most of the reactions on oleochemicals occura tt he fatty acidc arboxy groupa nd they are comparatively few examples on the alkyl chain.H owever,t he presence of double bond(s) in unsaturated fatty acid derivatives allows the installation of arange of organic functions [5] including aldehyde, [6] epoxide, [7] diol, [8] ketone and diketone, [9] ahydroxyketone, [10] carbonate, [11] among others. [12] More importantly,c leavage reactions-mainly using methylo leate as the archetype-can give access to building-blocksw ith higher added value, essentially for surfactants and polymer applications.…”
Section: Introductionmentioning
confidence: 99%
“…[13] Moreover, functional-ized aldehydes can be transformed to monomers for the preparationo fp olyesters and polyamidest hrough reduction or reductive amination,r espectively. [8] However,t here are not so many methods to produce aldehydes from vegetable oils or fatty acid derivatives. Thermal cracking of methyl ricinoleate obtained from castoro il produces bio-heptanal as ac o-product of nylon-11 (Rilsan )s ynthesis.…”
Section: Introductionmentioning
confidence: 99%