2022
DOI: 10.3390/coatings12121915
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Chemical Stability of Sputter Deposited Silver Thin Films

Abstract: Silver films with a thickness below 50 nanometer were deposited on glass using DC magnetron sputtering. The chemical stability of the films was investigated by exposure of the film to a droplet of a HCl solution in a humid atmosphere. The affected area was monitored with a digital microscope. The affected area increases approximately linearly with time which points to a diffusive mechanism. The slope of the area versus time plot, or the diffusivity, was measured as a function of the acid concentration, the pre… Show more

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Cited by 7 publications
(2 citation statements)
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“…Nevertheless, the anode thin film resistances mentioned above are all lower than the value of commercially available ITO, which is about 14 Ω/sq. This thin layer resistance is inversely proportional to the carrier mobility and conductivity, and the factors affecting the multilayer film conductivity include the thickness and surface roughness of the Ag layer [ 31 ]. It can be seen that, due to the thickness of the evaporated MoO 3 being 5 nm, the thin film resistance measured for ZnS/Ag/MoO 3 does not increase much compared with ZnS/Ag, so MoO 3 will not have a significant impact on the charge balance and electrical properties of OLEDs [ 32 ].…”
Section: Resultsmentioning
confidence: 99%
“…Nevertheless, the anode thin film resistances mentioned above are all lower than the value of commercially available ITO, which is about 14 Ω/sq. This thin layer resistance is inversely proportional to the carrier mobility and conductivity, and the factors affecting the multilayer film conductivity include the thickness and surface roughness of the Ag layer [ 31 ]. It can be seen that, due to the thickness of the evaporated MoO 3 being 5 nm, the thin film resistance measured for ZnS/Ag/MoO 3 does not increase much compared with ZnS/Ag, so MoO 3 will not have a significant impact on the charge balance and electrical properties of OLEDs [ 32 ].…”
Section: Resultsmentioning
confidence: 99%
“…Silver is the most commonly used noble metal, due to its more suitable optical properties [7,8], which allow the coatings to remain transparent in the visible range, while achieving a high infrared reflectance. The transparent thin layers are essential for adjusting the optical properties (often acting as an anti-reflective effect, to maximize visible transmission), but they also serve other functions, such as acting as a seed layer to improve silver deposition and enhance adhesion, or protecting the silver layer from exposure to the atmosphere [9][10][11][12][13].…”
Section: Introductionmentioning
confidence: 99%