Chemical Thermodynamic Properties of Aniline.

Recommended vapor pressures for aniline, nitromethane, 2-aminoethanol, and 1-methyl-2-pyrrolidone

“…(Fig. 9), only the vapor pressure data reported by Steele et al [13] were thermodynamically consistent with the enthalpies of vaporization [75,96] and heat capacities (Tables 6 to 8). Table 12 for aniline.…”

“…The agreement with the calorimetrically determined vaporization enthalpies is excellent. The deviations do not exceed 0.1 kJ·mol -1 for aniline when compared to the data [75,96] and 0.1 kJ·mol -1 and 0.2 kJ·mol -1 for nitromethane when compared to the data [31] and [35], respectively.…”

“…Compound For aniline, the recommendation by Zábranský et al [94] based on the data by Hatton et al [75], Nichols and Wadsö [76], and Steele et al [13] was retained. Zábranský et al [94] assigned uncertainty 0.3 % to the data covering temperature range from the normal melting point temperature 267.13 K [75] to 420 K (data are available up to 680 K, but these values are not relevant to this work).…”

Micro- and nano-sized peptidic assemblies prepared via solid-vapor approach: Morphological and spectroscopic aspects

“…2. Simply calculations using the Antoine equation log P ¼ A À B/(T À C) (where P ¼ pressure; T ¼ temperature; A, B and C are characteristic constants [43]) shows that the vapor pressure of aniline, at 98 C, is w0.055 atm. At the same temperature, water is very near to the boiling point which implies a very high rate of evaporation.…”

Thermodynamic and kinetic characteristics of liquid phase hydrogenation of substituted nitrobenzenes

“…To check the correctness of quantum chemical calculations, their results were compared with the thermodynamic functions of hydrogenation of NBA and NP isomers in the gas phase determined calori metrically [20][21][22][23]. The data presented in Fig.…”