Focusing on the photographic archive of Julián Carrillo (México), we study and characterize the photographic process of a set of 13 photographs dated between 1884 and 1925. By using infrared spectroscopic ellipsometry we classified a selected set of photographs according to the kind of binder used. Thus, we recognized for each photograph, the presence of proteins, and thus the particular photographic process. Furthermore, we have identified the presence of baryta layer, the use of plasticizer, and the eventual coating utilized to protect the photograph, whose composition was based in natural organic components, mainly shellac, beeswax, or camphor.