2010
DOI: 10.1063/1.3294880
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Chemiluminescence from the Ba(P3)+N2O→BaO(A Σ1+)+N2 reaction: Collision energy effects on the product rotational alignment and energy release

Abstract: Both fully dispersed unpolarized and polarized chemiluminescence spectra from the Ba((3)P)+N(2)O reaction have been recorded under hyperthermal laser-ablated atomic beam-Maxwellian gas conditions at three specific average collision energies E(c) in the range of 4.82-7.47 eV. A comprehensive analysis of the whole data series suggests that the A (1)Sigma(+)-->X (1)Sigma(+) band system dominates the chemiluminescence. The polarization results revealed that the BaO(A (1)Sigma(+)) product rotational alignment is in… Show more

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