Chemischer Informationsdienst
 1978
DOI: 10.1002/chin.197841244
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ChemInform Abstract: 4‐ALKOXY‐1‐PHENYL‐PHOSPHACYCLOHEXADIENE → 1‐ALKOXY‐1‐PHENYL‐Λ5‐PHOSPHORIN REARRANGEMENT

G. Maerkl1,
R. Liebl2,
A. Huettner3

Abstract: Die leicht zugänglichen 4‐substituierten 4‐Alkoxy‐1‐phenyl‐1‐phosphacyclohexadiene‐(2,5) (I) lagern sich in Gegenwart katalytischer Mengen p‐Toluolsulfonsäure zu den 1‐Alkoxy‐1‐phenyl‐ 5‐phosphorinen (II) um, den ersten C‐monosubstituierten K5 ‐Phosphorinen.

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