1988
DOI: 10.1002/chin.198810385
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ChemInform Abstract: (.+‐.)‐4‐Oxo‐9‐deoxy‐9‐azaprostaglandin I2 Derivatives. Very Stable Prostacyclin Analogs.

Abstract: Key steps in the synthesis of the title compounds (XII) are the preparation of the amide (III), its transformation to the lactam (IV) by reductive deacylation followed by stereoselective introduction of a hydroxyl group and attachment of the α‐chain to the thiolactam (IX) via formation of a thioether and subsequent Eschenmoser sulfide contraction.

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